专利名称:COBALT-BASED FISCHER-TROPSCH
SYNTHESIS CATALYST COATED WITHMESOPOROUS MATERIALS ANDPREPARATION METHOD THEREFOR
发明人:RAO, Shasha,SONG, Dechen,LIU,
Qianqian,ZHENG, Shenke
申请号:EP15783307.0申请日:20150206公开号:EP3135372A1公开日:20170301
专利附图:
摘要:A cobalt-based Fischer-Tropsch synthesis catalyst coated with mesoporousmaterials and preparation method therefor are disclosed. The catalyst comprises a silicacarrier surface-loaded with an active component of cobalt and a selective promoter ofzirconium; the outside of the active component of cobalt and the selective promoter of
zirconium is coated with a mesoporous material shell layer. The preparation methodcomprises preparing silica carrier loaded with zirconium, preparing an initial cobalt-basedFischer-Tropsch synthesis catalyst on the silica carrier base, formulating a precursorsolution of mesoporous materials, then dipping, crystallizing, washing, drying andcalcining to obtain the cobalt-based Fischer-Tropsch synthesis catalyst coated withmesoporous materials. The active component is coated and protected by themesoporous material shell layer, the thickness of the shell layer is controllable, thecatalyst has long service life, high reactivity and good stability. The pore structure ofmesoporous materials provides a channel for diffusing CO and H2, the selectivity of C5 +is high and the selectivity of methane is low. The catalyst is specially applicable to slurrybubble column reactors or continuously stirred tank reactors.
申请人:Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.
地址:T1 Jiangxia Avenue Miaoshan Development Zone Jiangxia District Wuhan, Hubei430223 CN
国籍:CN
代理机构:Zeuner Summerer Stütz
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